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Oils, Fats & Waxes

Ethyl hexanoate

CAS: 123-66-0

Overview

Ethyl hexanoate ( CAS 123-66-0 ), also known by its FEMA 2439 designation and commercially as ethyl caproate, is a fruity ester used as a flavoring agent and fragrance ingredient across food, cosmetic, and industrial applications.

Its characteristic apple-pineapple odor profile makes it a target compound for flavor houses and fragrance formulators sourcing aroma chemicals at scale. In food and beverage manufacturing, it functions as a flavoring agent.

It is used in fruit-type confectionery, alcoholic beverages, and dairy products where tropical and apple notes are required. Fragrance formulators incorporate it into personal care products including lotions, shampoos, and body washes.

These applications deliver light, fresh top notes to the consumer. As a synthetic ester, it also sees use as a lubricant additive and plasticizer component in specialty industrial formulations where low-viscosity ester chemistry is specified.

Flavor blenders reference its regulatory status when qualifying it for use in regulated food applications in the US market. The compound is supplied as a clear liquid in drum and IBC quantities suited to industrial procurement.

It is available in food-grade and fragrance-grade specifications, with FCC grade material commonly requested for flavor applications. Purity levels of 98% and above are standard for flavor and fragrance end uses.

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Physical Properties

Melting Point-67 °C
Boiling Point165.6 °C
Density0.83146 g/cm³ @ Temp: 70.00 °C
Flash Point121 °F
AppearanceCLEAR COLOURLESS LIQUID
ColorClear colorless
Odorat 1.00 % in dipropylene glycol. sweet fruity pineapple waxy green banana
FormLiquid
Water SolubilityINSOLUBLE
Vapor Pressure4hPa at 25℃
Refractive Indexn 20/D 1.407
Log P2.96 at 22.4℃

Safety & Handling

Warning GHS02 GHS09 Hazard Statements H226 Flammable liquid and vapor H401 Toxic to aquatic life H411 Toxic to aquatic life with long lasting effects Precautionary Statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P391 Collect spillage. P501 Dispose of contents/container in accordance with local regulations. P370+P378 Use … for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

Trade & Regulatory

HS Code29159000
UN Number3272
ADR Class3
Packing GroupIII
Storage Class3 - Flammable liquids
WGK (Germany)1

Other Names

n-Caproic acid ethyl ester | Hexanoic acidethyl ester | Ethyl n-hexanoate | Ethyl n-hexanoat | Ethyl hexoate | Ethyl hexanoate (caproate) | Ethyl ester of hexanoic acid

Related Products

Chemical Properties

CAS Number
123-66-0
EC Number
204-640-3
Mol. Weight
144.21
HS Code
29159000

Industries

Documentation