Overview
Potassium ferricyanide (CAS 13746-66-2 ), also known commercially as red prussiate, is an oxidizing salt used across industrial processes requiring controlled redox reactions. Its selectivity as an oxidant makes it a reliable reagent in both manufacturing and laboratory-scale operations.
In metal finishing and etching, it acts as a controlled oxidizing agent for blueprint development and photographic toning. These applications require precise image contrast and surface definition to ensure high-quality results in technical imaging.
Textile and leather processors use it in discharge printing and bleaching operations to selectively remove color from dyed substrates. This process allows for intricate patterns without degrading the structural integrity of the base material.
In mining and hydrometallurgy, it functions as a leaching or selective precipitation agent during precious metal recovery. This chemical property is essential for separating valuable minerals from complex ore matrices in industrial settings.
Pharmaceutical and analytical laboratories rely on it as a reagent for colorimetric assays and as an oxidant in the synthesis of active intermediates. It is a staple in research environments where consistent chemical behavior is mandatory.
Potassium ferricyanide is supplied as a crystalline powder or granules, typically in a bright red-orange form that aids visual quality verification. Technical grade is the standard commercial offering for large-scale industrial use.
High-purity reagent and ACS grades are available for laboratory and pharmaceutical procurement channels. These grades ensure compliance with strict analytical standards required for sensitive chemical testing and synthesis.
Bulk supply is common in 25 kg bags or fiber drums, with smaller packaging available for laboratory and specialty buyers. Proper storage in a cool, dry environment is recommended to maintain the stability of the crystalline structure.
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Physical Properties
| Melting Point | °Cd ec.) |
| Density | 1.822 g/cm³ |
| Appearance | orange to red crystals |
| Color | Orange to red |
| Odor | Odorless |
| Form | fine crystals |
| Water Solubility | 464 g/L (20 ºC) |
| Vapor Pressure | 0Pa at 20℃ |
| pH | 6-9 (25℃, 1M in H2O) |
Safety & Handling
Warning GHS07 GHS08 GHS09 Hazard Statements H302 Harmful if swallowed H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H361 Suspected of damaging fertility or the unborn child H411 Toxic to aquatic life with long lasting effects Precautionary Statements P203 Obtain, consult and follow expert instructions for use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P318 IF exposed or concerned, get medical advice. P319 Get medical advice/attention if you feel unwell. P321 Specific treatment (see … on this label). P330 Rinse mouth. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P264+P265 Wash … thoroughly after handling. P301+P317 Get emergency medical help. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P317 Get emergency medical help. P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Trade & Regulatory
| HS Code | 28372000 |
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| WGK (Germany) | 2 |
Other Names
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Chemical Properties
- CAS Number
- 13746-66-2
- EC Number
- 237-323-3
- Mol. Weight
- 329.24
- HS Code
- 28372000
- Category
- Heterocyclic Compounds