Overview
Polytetrahydrofuran (CAS 25190-06-1 ), commercially known as PTMEG or Polytetramethylene Ether Glycol, is a difunctional polyether diol used as a building block in high-performance polymer synthesis.
It provides the soft-segment component in polyurethane and elastomer systems, directly influencing flexibility, elongation, and low-temperature performance in finished materials.
In polyurethane manufacturing, PTMEG reacts with diisocyanates to produce elastic fibers such as spandex and Lycra, where its molecular weight grade determines the stretch-recovery characteristics.
Thermoplastic polyurethane (TPU) producers use it to engineer elastomers for automotive seals, hoses, and flexible tubing that must retain performance across a wide temperature range.
In the textile and apparel sector, PTMEG-based polyurethane urea is the standard intermediate for high-elasticity fabrics used in activewear and hosiery applications worldwide.
Lubricant formulators incorporate it as a plasticizing and carrier component in specialty greases and metalworking fluids where controlled viscosity and compatibility are required.
PTMEG is supplied as a waxy solid or viscous liquid depending on molecular weight, with common commercial grades at 650, 1000, 1800, and 2000 g/mol for industrial use.
Technical and industrial grades are standard; higher-purity grades are available for fiber and medical-grade polyurethane applications. Bulk supply is typically offered in heated drums.
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Physical Properties
| Melting Point | 20 °C |
| Boiling Point | >204 |
| Density | 0.978 g/cm³ @ Temp: 23 °C |
| Flash Point | >230 °F |
| Form | Fused mass |
| Water Solubility | <10g/L |
| Vapor Pressure | <0.01 mm Hg ( 25 °C) |
| Refractive Index | n 20/D 1.465 |
| pH | 7 (H2O, 20℃)Aqueous solution |
Safety & Handling
Warning GHS07 Hazard Statements H319 Causes serious eye irritation H412 Harmful to aquatic life with long lasting effects Precautionary Statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P501 Dispose of contents/container in accordance with local regulations. P264+P265 Wash … thoroughly after handling. P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Trade & Regulatory
| HS Code | 3907 20 20 |
| Storage Class | 11 - Combustible Solids |
| WGK (Germany) | 1 |
Other Names
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Chemical Properties
- CAS Number
- 25190-06-1
- EC Number
- 607-637-9
- Mol. Weight
- 146.23
- HS Code
- 3907 20 20
- Category
- Alcohols & Glycols