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Alcohols & Glycols

Polytetrahydrofuran

CAS: 25190-06-1

Overview

Polytetrahydrofuran (CAS 25190-06-1 ), commercially known as PTMEG or Polytetramethylene Ether Glycol, is a difunctional polyether diol used as a building block in high-performance polymer synthesis.

It provides the soft-segment component in polyurethane and elastomer systems, directly influencing flexibility, elongation, and low-temperature performance in finished materials.

In polyurethane manufacturing, PTMEG reacts with diisocyanates to produce elastic fibers such as spandex and Lycra, where its molecular weight grade determines the stretch-recovery characteristics.

Thermoplastic polyurethane (TPU) producers use it to engineer elastomers for automotive seals, hoses, and flexible tubing that must retain performance across a wide temperature range.

In the textile and apparel sector, PTMEG-based polyurethane urea is the standard intermediate for high-elasticity fabrics used in activewear and hosiery applications worldwide.

Lubricant formulators incorporate it as a plasticizing and carrier component in specialty greases and metalworking fluids where controlled viscosity and compatibility are required.

PTMEG is supplied as a waxy solid or viscous liquid depending on molecular weight, with common commercial grades at 650, 1000, 1800, and 2000 g/mol for industrial use.

Technical and industrial grades are standard; higher-purity grades are available for fiber and medical-grade polyurethane applications. Bulk supply is typically offered in heated drums.

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Physical Properties

Melting Point20 °C
Boiling Point>204
Density0.978 g/cm³ @ Temp: 23 °C
Flash Point>230 °F
FormFused mass
Water Solubility<10g/L
Vapor Pressure<0.01 mm Hg ( 25 °C)
Refractive Indexn 20/D 1.465
pH7 (H2O, 20℃)Aqueous solution

Safety & Handling

Warning GHS07 Hazard Statements H319 Causes serious eye irritation H412 Harmful to aquatic life with long lasting effects Precautionary Statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P501 Dispose of contents/container in accordance with local regulations. P264+P265 Wash … thoroughly after handling. P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code3907 20 20
Storage Class11 - Combustible Solids
WGK (Germany)1

Other Names

(2S)-2-butoxybutan-1-ol | Polytetramethylene ether glycol (ptmeg) | Polytetramethylene glycol | PTMEG

Related Products

Chemical Properties

CAS Number
25190-06-1
EC Number
607-637-9
Mol. Weight
146.23
HS Code
3907 20 20

Industries

Documentation