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Chelating Agents

Ferric ammonium citrate

CAS: 1185-57-5

Overview

Ferric ammonium citrate (CAS 1185-57-5 ), also known by the E-number E381 , is a water-soluble iron salt used as a bioavailable iron source and chelating agent across food, pharmaceutical, and industrial applications.

FAC delivers controlled iron supplementation and metal sequestration where inorganic iron salts would cause stability or compatibility issues. In food and beverage manufacturing, E381 functions as an iron fortification agent.

It is used in flour, cereals, and infant formula, meeting regulatory requirements for micronutrient enrichment. Pharmaceutical formulators use FAC as an iron source in oral supplements and hematinics.

This is particularly useful where solubility and tolerability profiles favor organic iron salts over sulfate alternatives. In water treatment, it acts as a coagulation aid and sequestrant for systems.

It prevents iron-related scaling and discoloration in distribution systems. Agricultural applications include its use as a foliar micronutrient supplement to correct iron deficiency in various crops.

This is effective in high-pH soils where inorganic iron becomes unavailable to plants. Ferric ammonium citrate is supplied as a brown or green powder, with color variation reflecting iron content.

Food-grade and USP / BP -compliant specifications are standard for pharmaceutical and fortification procurement. Technical-grade material is available for water treatment and agricultural use.

These materials are typically supplied in bulk quantities to meet industrial demand. The product ensures high purity and consistent performance across all specified chemical and industrial applications.

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Physical Properties

Melting Point>193°C (dec.)
Boiling Point498°C[at 101 325 Pa]
Density1.06[at 20°C]
AppearanceFerric ammonium citrate forms reddish brown flakes or grains, or a brownish-yellow powder. It has a slight ammonia odor. There is also a green form that is odorless.
ColorGreen
OdorOdorless to slight ammonia odor
Formpowder
Water Solubility1200 g/L (20 ºC)
Vapor Pressure0Pa@25°C
pH6-8 (100g/l, H2O, 20℃)
Log P-0.737 at 25℃

Safety & Handling

Warning GHS07 Hazard Statements H315 Causes skin irritation H319 Causes serious eye irritation Precautionary Statements P264 Wash … thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P321 Specific treatment (see … on this label). P264+P265 Wash … thoroughly after handling. P302+P352 IF ON SKIN: Wash with plenty of water. P332+P317 Get emergency medical help. P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29181500
UN Number9118
Storage Class11 - Combustible Solids
WGK (Germany)3

Other Names

iron(III) ammonium citrate | ammonium iron(III) citrate | Ammonium ferric citrate | Iron ammonium citrate | Ferri Seltz | Ferric ammonium citrategreen | Ammonii ferri citras | Ammonium iron(3+) citrate | FAC | E381

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Chemical Properties

CAS Number
1185-57-5
EC Number
214-686-6
Mol. Weight
265.00
HS Code
29181500

Industries

Documentation