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2-mercaptobenzothiazole

CAS: 149-30-4

Overview

2-Mercaptobenzothiazole (CAS 149-30-4 ), commonly known as MBT or Captax, is a primary accelerator and intermediate used across rubber processing, industrial preservation, and specialty chemical synthesis.

It activates sulfur vulcanization in elastomers and functions as a biocide and corrosion inhibitor in industrial fluid systems. In rubber and tire manufacturing, MBT accelerates sulfur crosslinking.

This improves cure efficiency and mechanical performance in finished goods for natural and synthetic elastomers. Industrial metalworking fluids and cooling water systems use it as a copper corrosion inhibitor.

It forms a protective complex on metal surfaces to extend fluid service life. As a biocide, it controls microbial growth in cutting fluids, adhesives, and polymer dispersions where biological fouling occurs.

MBT also serves as a key synthesis intermediate for benzothiazole-based accelerator derivatives, including MBTS and CBS. These are produced at scale for the global rubber chemicals market.

The product is supplied as a yellow to tan powder or as a sodium salt solution for fluid-system applications. Standard commercial grades include technical and rubber-grade specifications.

Purity typically ranges from 95% to 98% or higher depending on the specific application. Bulk supply is available in bags or drums, with technical-grade product being the dominant form traded.

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Physical Properties

Melting Point180.2-181.7 °C
Boiling Point223°C (rough estimate)
Density1.42 g/cm³
Flash Point243 °C
Appearancebeige or light yellow powder with a faint odour
ColorYellow
OdorOdorless
FormPowder
Water Solubility<0.1 g/100 mL at 19 ºC
Vapor Pressure<0.000003 hPa (25 °C)
Refractive Index1.6100 (estimate)
pH7 (0.12g/l, H2O, 25℃)
Log P2.86

Safety & Handling

Warning GHS07 GHS09 GHS08 Hazard Statements H317 May cause an allergic skin reaction H350 May cause cancer H351 Suspected of causing cancer H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects Precautionary Statements P203 Obtain, consult and follow expert instructions for use. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P318 IF exposed or concerned, get medical advice. P321 Specific treatment (see … on this label). P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P317 Get emergency medical help. P362+P364 Take off contaminated clothing and wash it before reuse.

Trade & Regulatory

HS Code29342020
UN Number3077
ADR Class9
Packing GroupIII
Storage Class11 - Combustible Solids
WGK (Germany)2

Other Names

Captax | benzothiazolyl mercaptan | 2-sulfanyl-13-benzothiazole | 2-MBT | 2-Benzothiazolethiol | 13-Benzothiazol-2-yl hydrosulfide | MBT | 13-Benzothiazole-2-thiol

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Chemical Properties

CAS Number
149-30-4
EC Number
205-736-8
Mol. Weight
167.3
HS Code
29342020

Industries

Documentation