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Oxidizers & Peroxides

3,5,5-Trimethylhexanoyl peroxide

CAS: 3851-87-4

Overview

3,5,5-Trimethylhexanoyl peroxide (CAS 3851-87-4 ), also supplied commercially as Di-(3,5,5-trimethylhexanoyl) peroxide, is an organic peroxide used as a free-radical initiator and curing agent across polymer and rubber manufacturing.

Its controlled decomposition profile makes it suitable for low-to-moderate temperature polymerization processes where precise initiation is required. In plastics manufacturing, it initiates free-radical polymerization of vinyl monomers.

This includes PVC, polystyrene, and acrylics, enabling consistent molecular weight distribution in bulk and suspension processes. Rubber compounders use it as a cross-linking agent to achieve targeted vulcanization profiles.

It is particularly effective in EPDM and silicone elastomers. In coatings and UV-cure adjacent systems, it drives radical-initiated cure of resin formulations where thermal activation is preferred over photoinitiators.

Adhesive and sealant producers apply it to cure acrylic and peroxide-curable systems requiring defined pot life and throughput temperatures. This peroxide is commercially available as a liquid solution.

It is most commonly supplied at 75% active concentration in a diluent to reduce handling hazards and improve dosing accuracy. Technical grade is the standard market offering for industrial applications.

Due to its classification as an organic peroxide, it is typically supplied in temperature-controlled packaging. Buyers should confirm defined storage requirements with their supplier to ensure product stability.

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Physical Properties

Boiling Point359.5±25.0 °C(Predicted)
Density0.942±0.06 g/cm3(Predicted)
Water Solubility10mg/L at 5℃
Vapor Pressure0.001Pa at 25℃
Log P3.34

Safety & Handling

Danger GHS02 GHS07 GHS08

Other Names

Peroxidebis(355-trimethyl-1-oxohexyl) | 355-trimethylhexanoyl 355-trimethylhexaneperoxoate | Di-(355-trimethylhexanoyl) peroxide

Related Products

Chemical Properties

CAS Number
3851-87-4
EC Number
223-356-0
Mol. Weight
314.5

Industries

Documentation