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Oxidizers & Peroxides

tert-butyl peroxyacetate

CAS: 107-71-1

Overview

Tert-butyl peroxyacetate (CAS 107-71-1 ), also known as tert-butyl peracetate and sold under the trade name Lupersol 70, is an organic peroxide used as a free-radical source in polymer manufacturing.

It delivers controlled radical generation across a defined temperature range, supporting both polymerization initiation and cross-linking processes for various industrial applications.

In plastics and polymer production, it initiates free-radical polymerization of vinyl monomers including styrene, acrylates, and vinyl acetate, enabling consistent molecular weight control.

Rubber and tire manufacturers use it as a cross-linking agent to cure elastomers, improving mechanical strength and heat resistance in finished compounds and specialty materials.

It also functions as a co-initiator in high-temperature polymerization systems where precise radical flux is required to meet specific product performance requirements and specifications.

Formulators working with polyethylene and specialty resins select it for grafting reactions where other peroxides would decompose too rapidly for the intended chemical process.

Tert-butyl peroxyacetate is supplied as a liquid solution, typically at 75% active concentration in a diluent to reduce handling hazards associated with the pure form.

Technical grade is the standard commercial offering, with supply governed by peroxide-specific transport and storage regulations. Packaging ranges from small drums to IBC containers.

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Physical Properties

Melting Point-20 °C
Boiling Point1.405 °C @ Press: 20 Torr
Density0.9415 g/cm³ @ Temp: 20 °C
Flash Point99 °F
Appearanceclear solution
ColorClear
FormSolution
Water Solubility3.878g/L at 25℃
Vapor Pressure1.966Pa at 25℃
Refractive Indexn 20/D 1.412
Log P1.6 at 25℃

Safety & Handling

Danger GHS02 GHS06 GHS07 GHS09 GHS01 Hazard Statements H201 (Deleted) Explosive; mass explosion hazard [Danger Explosives] H240 Heating may cause an explosion [Danger Self-reactive substances and mixtures; Organic peroxides] H319 Causes serious eye irritation [Warning Serious eye damage/eye irritation] H331 Toxic if inhaled [Danger Acute toxicity, inhalation] H335 May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

Trade & Regulatory

HS Code29159000
UN Number3103
ADR Class5.2
Storage Class5.2 - Organic peroxides and self-reacting hazardous materials
WGK (Germany)2

Other Names

tert-Butyl peracetate | t-Butyl peracetate | Lupersol 70 | t-Butyl peroxyacetate | Trigonox F-C50 | ETHANEPEROXOIC ACID11-DIMETHYLETHYL ESTER | Peroxyacetic acidtert-butyl ester | FJ3F3S50CS

Related Products

Chemical Properties

CAS Number
107-71-1
EC Number
203-514-5
Mol. Weight
132.16
HS Code
29159000

Industries

Documentation