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Polymers & Resins

Diethylene glycol diacrylate

CAS: 4074-88-8

Overview

Diethylene glycol diacrylate (CAS 4074-88-8 ), also referred to commercially as oxydiethylene diacrylate, is a bifunctional acrylate monomer used as a reactive crosslinker and diluent in UV- and peroxide-curable systems.

Its dual acrylate functionality enables rapid network formation, giving formulators control over cure speed, crosslink density, and final film hardness. In UV-curable coatings and inks, it acts as a reactive diluent.

This monomer reduces viscosity without introducing volatile organic compounds, while contributing to crosslink density in the cured film. Printing and packaging applications rely on it for fast-curing flexographic and screen inks.

Adhesion and abrasion resistance are critical performance targets in these applications. In adhesive and sealant formulations, it builds cohesive strength by tying polymer chains into tighter networks during cure.

Polymer manufacturers also incorporate it as a crosslinking comonomer in acrylic resins and hydrogel matrices. This is particularly useful where controlled swelling behavior is a specific formulation requirement.

The product is supplied as a clear liquid, typically inhibited with hydroquinone monomethyl ether to prevent premature polymerization during storage and transport. This ensures stability throughout the supply chain.

Technical and industrial grades are the standard market offering, with purity specifications commonly at 98% or higher. Packaging ranges from drums to IBC totes depending on the specific order volume required.

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Physical Properties

Melting Point>200°C/760mm
Boiling Point94 °C @ Press: 0.225 Torr
Density1.118 g/mL at 25 °C(lit.)
Flash Point>230 °F
Appearancecolourless liquid
ColorColorless to Almost colorless
Formclear liquid
Water SolubilitySlightly soluble in water (1-5g/100ml at 18°C).
Refractive Indexn 20/D 1.463(lit.)

Safety & Handling

Danger GHS06 GHS07 GHS05 GHS08 Hazard Statements H227 Combustible liquid H301 Toxic if swallowed H302 Harmful if swallowed H310 Fatal in contact with skin H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H361 Suspected of damaging fertility or the unborn child Precautionary Statements P203 Obtain, consult and follow expert instructions for use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P316 Get emergency medical help immediately. P317 Get emergency medical help. P318 IF exposed or concerned, get medical advice. P321 Specific treatment (see … on this label). P330 Rinse mouth. P363 Wash contaminated clothing before reuse. P403 Store in a well-ventilated place. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P264+P265 Wash … thoroughly after handling. P301+P316 Get emergency medical help immediately. P301+P317 Get emergency medical help. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P317 Get emergency medical help. P333+P317 Get emergency medical help. P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help. P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P362+P364 Take off contaminated clothing and wash it before reuse. P370+P378 Use … for extinction. P301+P330+P331 Rinse mouth. Do NOT induce vomiting. P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code2916.12.5050
UN Number2922
ADR Class8
Packing GroupIII
Storage Class6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
WGK (Germany)1

Other Names

Oxydiethylene acrylate | Oxydiethylene diacrylate | Diacrylate diethylene glycol | 2-Propenoic acid11′-(oxydi-21-ethanediyl) ester | Acrylic acidoxydiethylene ester

Related Products

Chemical Properties

CAS Number
4074-88-8
EC Number
223-791-6
Mol. Weight
214.21
HS Code
2916.12.5050

Industries

Documentation