Overview
Diphenylguanidine (CAS 102-06-7 ), commonly abbreviated as DPG and sold under the trade name Vulkazit, is a secondary accelerator used in rubber vulcanization. It activates primary accelerators and improves cure efficiency across a broad range of rubber compounds.
In tire manufacturing, DPG functions as a co-accelerator alongside thiazoles and sulfenamides, improving crosslink density and reducing cure time in both natural and synthetic rubber compounds.
It is used in industrial rubber goods, including belts, hoses, and seals, where consistent cure rates and mechanical performance are critical to product specification. In leather processing, DPG acts as a retanning auxiliary.
It serves as a pH modifier, influencing dye uptake and leather softness in finishing formulations. Printing ink and textile applications use DPG as a curing agent in certain resin systems where controlled crosslinking is required.
Diphenylguanidine is supplied as a white to off-white powder or as pre-dispersed granules suited for mixing operations. Standard commercial grades are available for rubber industry use, with product specifications covering purity.
Specifications typically cover melting point range and ash content. Technical grade is the predominant market form, with product conforming to established rubber chemical standards such as ISO and ASTM test methods.
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Physical Properties
| Melting Point | 150 °C |
| Boiling Point | 170 °C |
| Density | 1.19 g/cm³ |
| Flash Point | 170°C |
| Appearance | white or cream powder with a slight odour |
| Color | Pale Cream |
| Odor | wh. powd., bitter taste, sl. odor |
| Form | Powder |
| Water Solubility | slightly soluble |
| Vapor Pressure | 0Pa at 25℃ |
| Refractive Index | 1.6000 (estimate) |
| pH | 10.2 (10g/l, H2O) |
| Log P | 2.42 at 21.1℃ |
Safety & Handling
Danger GHS07 GHS08 GHS09 GHS06 Hazard Statements H301 H301 H302 H302 H315 H315 H319 H319 H320 H320 H335 H335 H336 H336 H361 H361 H401 H401 H411 H411 Precautionary Statements P203 P203 P261 P261 P264 P264 P270 P270 P271 P271 P273 P273 P280 P280 P318 P318 P319 P319 P321 P321 P330 P330 P391 P391 P405 P405 P501 P501 P264+P265 P264+P265 P301+P316 P301+P316 P301+P317 P301+P317 P302+P352 P302+P352 P304+P340 P304+P340 P332+P317 P332+P317 P337+P317 P337+P317 P362+P364 P362+P364 P403+P233 P403+P233 P305+P351+P338 P305+P351+P338
Trade & Regulatory
| HS Code | 29252000 |
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
| WGK (Germany) | 2 |
Other Names
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Chemical Properties
- CAS Number
- 102-06-7
- EC Number
- 203-002-1
- Mol. Weight
- 211.26
- HS Code
- 29252000
- Category
- Amines