Overview
Phosphonomethyliminodiacetic acid (CAS 5994-61-6 ), commonly abbreviated as PMIDA, is a phosphonate-based chelating agent used across industrial water treatment, agriculture, and specialty chemical manufacturing.
Its primary commercial role is sequestering metal ions and inhibiting scale and corrosion in process systems. PMIDA is also a key intermediate in the synthesis of glyphosate herbicide, giving it significant relevance.
In agrochemical manufacturing, PMIDA serves as the direct precursor to glyphosate, making it a critical raw material for herbicide producers operating at scale. It is essential for high-volume production lines.
Water treatment formulators incorporate it into corrosion and scale inhibitor blends for cooling towers, boilers, and oilfield injection systems where metal ion control is critical for maintaining equipment integrity.
In textile and paper processing, it sequesters calcium and magnesium ions to prevent interference during bleaching and dyeing operations. This ensures consistent quality and color uniformity in the final products.
Oil and gas operators use PMIDA-based formulations to control mineral scale deposition in pipelines and production equipment. This application is vital for preventing flow restrictions and maintaining operational efficiency.
PMIDA is supplied as a white to off-white crystalline powder. Technical grade is the standard commercial form, with purity levels typically specified at 98% or higher for agrochemical intermediate use.
Bulk quantities are available for industrial procurement, with packaging options ranging from multi-layer bags to IBC containers depending on volume requirements and logistical needs for global distribution.
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Physical Properties
| Melting Point | 210 °C |
| Boiling Point | 585.9±60.0 °C(Predicted) |
| Density | 1.792±0.06 g/cm3(Predicted) |
| Appearance | White to off-white Solid |
| Form | Crystalline |
| Vapor Pressure | 0Pa at 45℃ |
Safety & Handling
Danger GHS05 Hazard Statements H314 Causes severe skin burns and eye damage Precautionary Statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash … thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P316 Get emergency medical help immediately. P321 Specific treatment (see … on this label). P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301+P330+P331 Rinse mouth. Do NOT induce vomiting. P302+P361+P354 IF ON SKIN: Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Trade & Regulatory
| UN Number | 3261 |
| ADR Class | 8 |
| Packing Group | III |
| Storage Class | 11 - Combustible Solids |
| WGK (Germany) | 1 |
Other Names
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Chemical Properties
- CAS Number
- 5994-61-6
- EC Number
- 227-824-5
- Mol. Weight
- 227.11
- Category
- Organic Acids