Overview
Octamethylcyclotetrasiloxane (CAS 556-67-2 ), commonly abbreviated as D4, is a cyclic siloxane monomer used as a key building block in silicone polymer synthesis. It functions as a reactive intermediate and processing aid across coatings, personal care, and polymer manufacturing.
In silicone elastomer and sealant production, D4 undergoes ring-opening polymerization to produce polydimethylsiloxane chains of controlled molecular weight. Personal care formulators use it as a carrier and emollient base in hair conditioners and skin creams.
In these applications, it delivers a smooth, non-greasy skin feel that supports product aesthetics. In industrial coatings and release liners, D4 acts as a surface modifier and crosslinking precursor, improving substrate wetting and film durability.
Adhesive and sealant manufacturers also use it as a reactive diluent to control viscosity and cure behavior in silicone formulations. D4 is supplied as a clear, low-viscosity liquid in drum and IBC quantities for industrial buyers.
Bulk tanker options are available for high-volume requirements. Standard supply grades include technical and polymer-grade specifications, with purity typically at 99% or higher to ensure consistent performance in chemical synthesis.
Buyers should confirm regulatory compliance status for their target market, particularly for personal care applications. D4 is subject to concentration restrictions in certain jurisdictions, requiring careful formulation and adherence to local safety standards.
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Physical Properties
| Melting Point | 17.5 °C |
| Boiling Point | 175 °C |
| Density | 0.9558 g/cm³ |
| Flash Point | 140 °F |
| Appearance | Colorless clear liquid |
| Color | colorless |
| Form | liquid |
| Water Solubility | INSOLUBLE |
| Vapor Pressure | 1.32hPa at 25℃ |
| Refractive Index | n 20/D 1.396(lit.) |
| Log P | 6.98 at 21.7℃ |
Safety & Handling
Warning GHS08 GHS09 GHS02 Hazard Statements H226 Flammable liquid and vapor H361 Suspected of damaging fertility or the unborn child H410 Very toxic to aquatic life with long lasting effects H413 May cause long lasting harmful effects to aquatic life Precautionary Statements P203 Obtain, consult and follow expert instructions for use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P318 IF exposed or concerned, get medical advice. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P370+P378 Use … for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
Trade & Regulatory
| HS Code | 29319090 |
| UN Number | 1993 |
| ADR Class | 3 |
| Packing Group | III |
| Storage Class | 3 - Flammable liquids |
| WGK (Germany) | 1 |
Other Names
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Chemical Properties
- CAS Number
- 556-67-2
- EC Number
- 209-136-7
- Mol. Weight
- 296.61
- HS Code
- 29319090
- Category
- Silicones & Silicates