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Silicones & Silicates

Octamethylcyclotetrasiloxane

CAS: 556-67-2

Overview

Octamethylcyclotetrasiloxane (CAS 556-67-2 ), commonly abbreviated as D4, is a cyclic siloxane monomer used as a key building block in silicone polymer synthesis. It functions as a reactive intermediate and processing aid across coatings, personal care, and polymer manufacturing.

In silicone elastomer and sealant production, D4 undergoes ring-opening polymerization to produce polydimethylsiloxane chains of controlled molecular weight. Personal care formulators use it as a carrier and emollient base in hair conditioners and skin creams.

In these applications, it delivers a smooth, non-greasy skin feel that supports product aesthetics. In industrial coatings and release liners, D4 acts as a surface modifier and crosslinking precursor, improving substrate wetting and film durability.

Adhesive and sealant manufacturers also use it as a reactive diluent to control viscosity and cure behavior in silicone formulations. D4 is supplied as a clear, low-viscosity liquid in drum and IBC quantities for industrial buyers.

Bulk tanker options are available for high-volume requirements. Standard supply grades include technical and polymer-grade specifications, with purity typically at 99% or higher to ensure consistent performance in chemical synthesis.

Buyers should confirm regulatory compliance status for their target market, particularly for personal care applications. D4 is subject to concentration restrictions in certain jurisdictions, requiring careful formulation and adherence to local safety standards.

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Physical Properties

Melting Point17.5 °C
Boiling Point175 °C
Density0.9558 g/cm³
Flash Point140 °F
AppearanceColorless clear liquid
Colorcolorless
Formliquid
Water SolubilityINSOLUBLE
Vapor Pressure1.32hPa at 25℃
Refractive Indexn 20/D 1.396(lit.)
Log P6.98 at 21.7℃

Safety & Handling

Warning GHS08 GHS09 GHS02 Hazard Statements H226 Flammable liquid and vapor H361 Suspected of damaging fertility or the unborn child H410 Very toxic to aquatic life with long lasting effects H413 May cause long lasting harmful effects to aquatic life Precautionary Statements P203 Obtain, consult and follow expert instructions for use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof [electrical/ventilating/lighting/…] equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P318 IF exposed or concerned, get medical advice. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P370+P378 Use … for extinction. P403+P235 Store in a well-ventilated place. Keep cool. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.

Trade & Regulatory

HS Code29319090
UN Number1993
ADR Class3
Packing GroupIII
Storage Class3 - Flammable liquids
WGK (Germany)1

Other Names

cyclic dimethylsiloxane tetramer | 22446688-octamethyl-13572468-tetroxatetrasilocane | 22446688-octamethyl-13572468-tetraoxatetrasilocane | cyclomethicone 4 | Cyclotetrasiloxaneoctamethyl- | OMCTS | NUC silicone VS 7207 | Union carbide 7207 | D4

Related Products

Chemical Properties

CAS Number
556-67-2
EC Number
209-136-7
Mol. Weight
296.61
HS Code
29319090

Industries

Documentation