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Oils, Fats & Waxes

Tributyl citrate

CAS: 77-94-1

Overview

Tributyl citrate (CAS 77-94-1 ), commonly referred to as TBC or butyl citrate, is a citrate ester plasticizer used across polymer processing, personal care, and food-contact applications.

It functions primarily as a plasticizer and stabilizer, imparting flexibility and processing performance to polymer systems while meeting low-toxicity requirements that restrict alternatives.

In PVC and cellulose-based polymer formulations, TBC improves film flexibility and elongation, making it a preferred choice for food-contact packaging and medical tubing.

It is also used in children's products where regulatory compliance limits phthalate use. Personal care formulators incorporate it into nail lacquers and film-forming cosmetic products.

As a plasticizing agent, it supports adhesion and wear performance. In food-grade contexts, TBC functions as a humectant and stabilizer in flavor encapsulation and coating systems.

It also acts as an antioxidant synergist in fat-containing formulations, helping to extend shelf life in processed food applications. The material is supplied as a clear, low-viscosity liquid.

Food-grade and technical-grade specifications are both commercially available, with food-grade material produced to FCC standards for regulated applications.

Buyers sourcing for EU food-contact or cosmetic end uses should confirm compliance documentation against relevant regional regulations to ensure full safety and quality standards.

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Physical Properties

Melting Point-20 °C
Boiling Point327 °C
Density1.043 g/mL at 20 °C(lit.)
Flash Point300 °C
AppearanceColorless or pale-yellow, stable, odorless, nonvolatile liquid. Practically insoluble in water. Combustible.
ColorClear
Odorodorless
FormLiquid
Water Solubilityinsoluble
Refractive Indexn 20/D 1.445
Log P4.324 (est)

Safety & Handling

Danger GHS05 Hazard Statements H318 Causes serious eye damage Precautionary Statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P317 Get emergency medical help. P264+P265 Wash … thoroughly after handling. P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code29181500
UN Number2811
ADR Class6.1
Packing GroupII
WGK (Germany)3

Other Names

Butyl citrate | tributyl 2-hydroxypropane-123-tricarboxylate | Tri-n-butyl citrate | Citroflex 4 | Citric acidtributyl ester | 123-Propanetricarboxylic acid2-hydroxy-tributyl ester | Morflex tbc | 123-Propanetricarboxylic acid2-hydroxy-123-tributyl ester | TBC

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Chemical Properties

CAS Number
77-94-1
EC Number
201-071-2
Mol. Weight
360.4
HS Code
29181500

Industries

Documentation