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Flame Retardants

Tetrabromophthalic anhydride

CAS: 632-79-1

Overview

Tetrabromophthalic anhydride (CAS 632-79-1 ), commonly abbreviated as TBPA and marketed under the trade name FireMaster PHT 4, is a reactive and additive bromine-based flame retardant used across plastics, electronics, and textile manufacturing.

Its high bromine content makes it effective at meeting stringent flammability standards in demanding end-use applications. In electronics, TBPA is incorporated into epoxy resins and printed circuit board laminates.

This allows manufacturers to achieve UL 94 flame retardancy ratings required by component manufacturers. Polyester and polyurethane foam producers use it as a reactive intermediate, chemically bonding it into the polymer backbone.

This process helps to reduce migration and improve durability of flame retardant performance. Textile and upholstery back-coating formulations use TBPA-derived diols to meet fire safety regulations for commercial furnishings.

It is also utilized for transportation seating. In rigid and flexible polymer systems, it functions as both a processing additive and a reactive monomer, giving formulators flexibility in how flame retardancy is built.

TBPA is supplied as an off-white to pale yellow crystalline powder. It is available in technical grade, with purity specifications typically at 98% or higher depending on specific industrial application requirements.

Packaging options commonly include 25 kg bags and bulk quantities suited to industrial procurement volumes. This ensures a reliable supply chain for large-scale manufacturing operations across various global sectors.

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Physical Properties

Melting Point279.5-280.5 °C
Boiling Point540.5±50.0 °C(Predicted)
Density2.87
Appearancewhite to light yellow powder
ColorWhite to light yellow
FormPowder
Water Solubilityhydrolysis
Vapor Pressure0.11 mm Hg ( 180 °C)
Refractive Index1.5000 (estimate)
Log P2.27 at 40℃

Safety & Handling

Warning GHS07 Hazard Statements H317 May cause an allergic skin reaction Precautionary Statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P321 Specific treatment (see … on this label). P501 Dispose of contents/container in accordance with local regulations. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P317 Get emergency medical help. P362+P364 Take off contaminated clothing and wash it before reuse.

Trade & Regulatory

HS Code29173911
Storage Class11 - Combustible Solids
WGK (Germany)2

Other Names

FireMaster PHT 4 | Tetrabromophthalic acid anhydride | Phthalic anhydridetetrabromo- | 13-Isobenzofurandione4567-tetrabromo- | Saytex RB 49 | PHT 4 | 4567-Tetrabromo-13-isobenzofurandione | TBPA

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Chemical Properties

CAS Number
632-79-1
EC Number
211-185-4
Mol. Weight
463.70
HS Code
29173911

Industries

Documentation