Overview
Methacrylic anhydride (CAS 760-93-0 ), also known as methacryloyl anhydride, is a reactive acylating agent used to introduce methacryloyl functional groups onto hydroxyl- or amine-bearing substrates.
It enables the synthesis of polymerizable macromonomers and modified polymers across specialty chemical manufacturing. In polymer chemistry, it is used to functionalize natural and synthetic backbones.
This includes cellulose, chitosan, and polyols, creating UV-curable or thermally crosslinkable materials for coatings, hydrogels, and resins. Personal care formulators use methacrylated intermediates derived from this reagent.
These intermediates help build film-forming polymers and crosslinked networks in hair fixatives and skin-contact materials. In dental and biomedical polymer applications, it serves as a key reagent.
It is used for producing methacrylated monomers used in adhesive and matrix formulations. Specialty flavor and fragrance synthesis also draws on its acylating reactivity to produce ester intermediates.
These processes occur at both laboratory and pilot scale. The product is supplied as a liquid, typically with inhibitor added to prevent premature polymerization during storage and transport.
Technical and reagent grades are the most commonly available, with purity levels generally ranging from 94% to 99%+. Packaging options typically include drums and intermediate bulk containers.
Industrial quantities are standard, with smaller laboratory-scale packaging available from fine chemical suppliers. This ensures flexibility for various manufacturing and research requirements.
Contact us for supply of Methacrylic anhydride
Physical Properties
| Melting Point | -20°C |
| Boiling Point | 45-47 °C @ Press: 2 Torr |
| Density | 1.035 g/cm³ |
| Flash Point | 184 °F |
| Appearance | liquid |
| Color | Colorless to Light yellow to Light orange |
| Form | clear liquid |
| Water Solubility | 98g/L at 20℃ |
| Vapor Pressure | 90Pa at 20℃ |
| Refractive Index | n 20/D 1.453(lit.) |
| Log P | 1.23 |
Safety & Handling
Danger GHS05 GHS06 GHS07 Hazard Statements H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H332 Harmful if inhaled H335 May cause respiratory irritation H302+H332 Harmful if swallowed or if inhaled Precautionary Statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P316 Get emergency medical help immediately. P317 Get emergency medical help. P319 Get medical advice/attention if you feel unwell. P321 Specific treatment (see … on this label). P330 Rinse mouth. P405 Store locked up. P501 Dispose of contents/container in accordance with local regulations. P264+P265 Wash … thoroughly after handling. P301+P317 Get emergency medical help. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+P317 Get emergency medical help. P333+P317 Get emergency medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P305+P354+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Trade & Regulatory
| HS Code | 29161900 |
| UN Number | 3265 |
| ADR Class | 8 |
| Packing Group | II |
| Storage Class | 10 - Combustible liquids |
| WGK (Germany) | 1 |
Other Names
Related Products
Chemical Properties
- CAS Number
- 760-93-0
- EC Number
- 212-084-8
- Mol. Weight
- 154.16
- HS Code
- 29161900
- Category
- Monomers & Building Blocks