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Salts & Minerals

Monoammonium phosphate

CAS: 7722-76-1

Overview

Monoammonium phosphate (CAS 7722-76-1 ), commonly known as MAP or designated E342 in food applications, is an inorganic ammonium salt used industrially as a flame retardant and pH buffering agent.

It delivers both nitrogen and phosphorus in a single compound, making it a practical input across agriculture, construction, and industrial processing. In agriculture, MAP is a high-analysis fertilizer applied directly to soil.

It can be dissolved for fertigation, supplying phosphorus and nitrogen in plant-available form. Flame retardant formulations for textiles, paper, and cellulosic materials rely on MAP to interrupt combustion at the fiber level.

This helps in meeting fire safety specifications in treated fabrics and packaging. In construction, it is incorporated into intumescent coatings and fire-retardant board treatments where controlled char formation is required.

Buffer solutions and pH adjustment processes in leather processing and industrial manufacturing also use MAP to maintain consistent process conditions. Monoammonium phosphate is supplied as a white crystalline powder or granule.

Granular forms predominate in agricultural supply chains. Standard grades include technical, food-grade, and fertilizer-grade, each carrying distinct purity and contaminant thresholds for various industrial uses.

Agricultural MAP is typically specified at 11-52 (11% N, 52% P₂O₅) and is available in bulk, supersack, and bagged formats. These options ensure flexibility for large-scale industrial and agricultural operations.

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Physical Properties

Melting Point190 °C
Boiling Point376.1 °C (decomp)
Density1.803 g/cm³
AppearanceAmmonium phosphate is a white crystalline or powdery substance.
ColorWhite or colorless
Odorbrilliant wh. cryst. or powd., odorless
FormSolid
Water Solubility368 g/L (20 ºC)
Vapor Pressure0.066 hPa (125 °C)
Refractive Index1.525
pH3.8-4.4 (25℃, 50mg/mL in H2O)
Log P-2.148 (est)

Safety & Handling

Warning GHS07 Hazard Statements H319 Causes serious eye irritation Precautionary Statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P264+P265 Wash … thoroughly after handling. P337+P317 If eye irritation persists: Get medical advice/attention. Get emergency medical help. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Trade & Regulatory

HS Code31054000
UN Number3264
Storage Class11 - Combustible Solids
WGK (Germany)1

Other Names

Primary ammonium phosphate | Phosphoric acidmonoammonium salt | NH4H2PO4 | Monobasic ammonium phosphate | Monoammonium orthophosphate | Monoammonium hydrogen phosphate | Monoammonium dihydrogen phosphate | Monoammonium dihydrogen orthophosphate | MAP | E342

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Chemical Properties

CAS Number
7722-76-1
EC Number
231-764-5
Mol. Weight
115.03
HS Code
31054000

Industries

Documentation